英语翻译The diamine in 3 was synthesized by diaza-Cope rearrangement reaction in a one-pot reaction (Scheme 1).Sequential addition of the two aldehydes to 4 results in efficient formation of the mixed diimine (6) followed by the rearrangement rea

英语翻译The diamine in 3 was synthesized by diaza-Cope rearrangement reaction in a one-pot reaction (Scheme 1).Sequential addition of the two aldehydes to 4 results in efficient formation of the mixed diimine (6) followed by the rearrangement rea
英语翻译
The diamine in 3 was synthesized by diaza-Cope rearrangement reaction in a one-pot reaction (Scheme 1).Sequential addition of the two aldehydes to 4 results in efficient formation of the mixed diimine (6) followed by the rearrangement reaction to give 7.The two resonance-assisted hydrogen bonds in 7 drive the rearrangement
reaction to completion.We first synthesized a Co(III) complex of 7 using pyridine as a base.The crystal structure of the Co(III) complex (Figure 1) shows that the quinoline group coordinates to the metal,thereby forcing the nitrophenyl group to occupy the axial position as desired.Interestingly,a pyridine molecule is coordinated
to the cobalt complex and positioned almost parallel to the nitrophenyl group.The two groups are about 3.26-3.90 A apart.

英语翻译The diamine in 3 was synthesized by diaza-Cope rearrangement reaction in a one-pot reaction (Scheme 1).Sequential addition of the two aldehydes to 4 results in efficient formation of the mixed diimine (6) followed by the rearrangement rea
在3二胺合成了二氮杂-应付在一锅煮反应（图1）重排反应.除了这两个序列醛4结果在有效形成混合二亚胺（六）重排反应,随后给予7.这两个共振协助7车道氢键重排
反应完成.我们首先合成了7钴（Ⅲ）配合物吡啶为基地.的CO（Ⅲ）配合物（图1）的晶体结构表明,喹啉组坐标,以金属,从而迫使硝基苯集团占据轴向位置应有的作用.有趣的是,吡啶分子协调复杂的钴和定位几乎平行的硝基苯组,两组相隔约3.26-3.90.

在3双的反应,合成了diaza-Cope重排反应在锅方案1)。序贯增加了两个醛到4导致具有高效的可构造性的混合diimine(6),接着重排反应给7。这两个resonance-assisted氢键重新排列在7开车
反应完成。我们首先合成了一有限公司(3)复杂的7使用吡啶为基础。晶体结构公司(3)复杂的(图1)表明,喹集团坐标金属,从而迫使nitrophenyl集团占据轴向位置作为一整段使用...

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在3双的反应,合成了diaza-Cope重排反应在锅方案1)。序贯增加了两个醛到4导致具有高效的可构造性的混合diimine(6),接着重排反应给7。这两个resonance-assisted氢键重新排列在7开车
反应完成。我们首先合成了一有限公司(3)复杂的7使用吡啶为基础。晶体结构公司(3)复杂的(图1)表明,喹集团坐标金属,从而迫使nitrophenyl集团占据轴向位置作为一整段使用。有趣的是,吡啶分子协调
对钴复杂和定位几乎平行于nitrophenyl组。这两组是关于3.26-3.90一个分开。
网上看到的。。。。

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