英语翻译The 1H NMR spectra of complexes 1 and 2 are shown in Fig.1.The proton质子 chemical shifts are assigned with the influence of steric空间,inductive引入 and conjugative共轭 effects and compared with those of similar compounds [18].Fo
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英语翻译The 1H NMR spectra of complexes 1 and 2 are shown in Fig.1.The proton质子 chemical shifts are assigned with the influence of steric空间,inductive引入 and conjugative共轭 effects and compared with those of similar compounds [18].Fo
英语翻译
The 1H NMR spectra of complexes 1 and 2 are shown in Fig.1.The proton质子 chemical shifts are assigned with the influence of steric空间,inductive引入 and conjugative共轭 effects and compared with those of similar compounds [18].For each of the two complexes,two sets of NMR signals were observed.One set corresponds to the bpy or dmb ligand,and the other set corresponds to the PyIP ligand.The proton resonance on the nitrogen atom of the PyIP imidazole ring was not observed,because the proton is active and exchanges quickly between the two nitrogen atoms of the imidazole咪唑 ring.Owing to the repulsive排斥的 interaction between two methyl substituent of each dmb ligand,along with the consideration考虑,原因 of the bpy in complex 1,the chemical shifts of the protons located in the bipyridine双吡啶ring of dmb are totally split in complex 2.
英语翻译The 1H NMR spectra of complexes 1 and 2 are shown in Fig.1.The proton质子 chemical shifts are assigned with the influence of steric空间,inductive引入 and conjugative共轭 effects and compared with those of similar compounds [18].Fo
1H NMR 合成物 1 和 2 的频谱在图 1 被显示.质子质子化学的变化与空间排列空间的影响力、归纳的引入和 conjugative 共轭效果一起分配而且与相似化合物 [18] 的相较.对于每一个这二个合成物,二组 NMR 信号被观察了.一组符合 bpy 或者 dmb ligand,和另一个组符合 PyIP ligand.因为质子是活跃的而且很快地在 imidazole 咪唑戒指的这二粒氮原子之间交换,所以 PyIP imidazole 戒指的在氮原子上的质子共呜没被观察.由于逐退的排斥交互作用在每 dmb ligand 的二个甲基取代之间,连同 bpy 的考量考虑,原因一起在合成物中 1,在 bipyridine 双吡啶 dmb 的戒指中的位于的质子的化学变化完全地在合成物中被分离 2.
金山快译